The Nix expressions for the X.org packages reside in <filename>pkgs/servers/x11/xorg/default.nix</filename>. This file is automatically generated from lists of tarballs in an X.org release. As such it should not be modified directly; rather, you should modify the lists, the generator script or the file <filename>pkgs/servers/x11/xorg/overrides.nix</filename>, in which you can override or add to the derivations produced by the generator.
For each of the tarballs in the <filename>.list</filename> files, the script downloads it, unpacks it, and searches its <filename>configure.ac</filename> and <filename>*.pc.in</filename> files for dependencies. This information is used to generate <filename>default.nix</filename>. The generator caches downloaded tarballs between runs. Pay close attention to the <literal>NOT FOUND: <replaceable>name</replaceable></literal> messages at the end of the run, since they may indicate missing dependencies. (Some might be optional dependencies, however.)
<filename>extra.list</filename> contains libraries that aren’t part of X.org proper, but are closely related to it, such as <literal>libxcb</literal>. <filename>old.list</filename> contains some packages that were removed from X.org, but are still needed by some people or by other packages (such as <varname>imake</varname>).
If the expression for a package requires derivation attributes that the generator cannot figure out automatically (say, <varname>patches</varname> or a <varname>postInstall</varname> hook), you should modify <filename>pkgs/servers/x11/xorg/overrides.nix</filename>.